RECENT ADVANCES IN THE SYNTHESIS OF SULFOXIDES FROM SULFIDES

Producción CyT

Artículo

Autoría

MATA, ERNESTO GABINO

Fecha

1996

Editorial y Lugar de Edición

TAYLOR & FRANCIS LTD

Revista

PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS, vol. 117 (pp. 231-286) TAYLOR & FRANCIS LTD

Resumen Información suministrada por el agente en SIGEVA

This review deals with the various recent advances in the selective oxidation of sulfides to sulfoxides. Non-stereoselective, diastereoselective as well as enantioselective methods are covered. A considerable number of new oxidizing agents have been reported in the last ten to twelve years including those aiming to replace m-chloroperbenzoic acid as the classical sulfide oxidant: Oxone" dimethyldioxirane, among others. Chiral sulfoxides are especially important in modem asymmetric synthesi... This review deals with the various recent advances in the selective oxidation of sulfides to sulfoxides. Non-stereoselective, diastereoselective as well as enantioselective methods are covered. A considerable number of new oxidizing agents have been reported in the last ten to twelve years including those aiming to replace m-chloroperbenzoic acid as the classical sulfide oxidant: Oxone" dimethyldioxirane, among others. Chiral sulfoxides are especially important in modem asymmetric synthesis. their obtention from prochiral sulfides by Davis' oxaziridines and modifications of Sharpless procedure are discussed, along with other less common methods. The most newly reported microbiological and enzymatic oxidations are also included.

Ver más Ver menos

Palabras Clave

sulfoxidesoxidation