Producción CyT
Artículo
Autoría
Maria Virginia Mirifico
;
Jose Alberto Caram
;
Ana Maria Gennaro
;
COBOS, CARLOS JORGE
;
Enrique Julio Vasini
Fecha
2011
Editorial y Lugar de Edición
JOHN WILEY & SONS LTD
Revista
JOURNAL OF PHYSICAL ORGANIC CHEMISTRY,
vol. 24
(pp. 1039-1044)
JOHN WILEY & SONS LTD
Resumen
Información suministrada por el agente en
SIGEVA
Radical anions from several 3,4-aryl-disubstituted derivatives of 1,2,5-thiadiazole 1,1-dioxide were accumulated through chemical reduction of the substrates in aprotic solvents. The radical anions were characterized by electron spin resonance and cyclic voltammetry. DFT theoretical calculations were also performed for the 3,4-diphenyl derivative. The course of the reductions was followed using cyclic voltammetry. Uncommon reductants, such as amides, were found to be effective under certain con...
Radical anions from several 3,4-aryl-disubstituted derivatives of 1,2,5-thiadiazole 1,1-dioxide were accumulated through chemical reduction of the substrates in aprotic solvents. The radical anions were characterized by electron spin resonance and cyclic voltammetry. DFT theoretical calculations were also performed for the 3,4-diphenyl derivative. The course of the reductions was followed using cyclic voltammetry. Uncommon reductants, such as amides, were found to be effective under certain conditions. Copyright 2010 John Wiley & Sons, Ltd.
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Palabras Clave
ESRcyclic voltammetryaliphatic amides1,2,5-thiadiazolesradical anions