Producción CyT
Advancements in Quasi-Solid-State Li Batteries: A Rigid Hybrid Electrolyte Using LATP Porous Ceramic Membrane and Infiltrated Ionic Liquid
Artículo
Autoría:
REINOSO, DEBORATH MARIANA ; de la Torre-Gamarra, Carmen ; Fernández-Ropero, Antonio J. ; Levenfeld, Belén ; Várez, AlejandroFecha:
2024Editorial y Lugar de Edición:
American Chemical SocietyRevista:
ACS Applied Energy Materials, vol. 7 American Chemical SocietyResumen *
Despite the progress made in Li-ion battery components, technology still faces major challenges. Among them, the development of novel electrolytes with promising characteristics is required for next-generation energy storage devices. In this work, rigid hybrid electrolytes have been prepared by infiltration of an ionic liquid solution (Pyr14TFSI) with a lithium salt (LiTFSI) into a sintered LATP ion-conducting porous ceramic. The porous ceramic 3D network was obtained via solid-state sintering of LATP powders mixed with a small amount of corn starch as pore former. A synergetic effect between the ionic liquid and support was evidenced. The resultant quasi-solid-state hybrid electrolytes exhibit high ionic conductivity (∼10-3 S·cm-1 at 303 K), improved ion transfer number, tLi+, and a wide electrochemical window of 4.7-4.9 V vs Li+/Li. The LATP porosity plays a critical role in the free Li+ charge because it favors higher TFSI- confinement in the ceramic interfaces, which consequently positively influences tLi+ and ionic conductivity. Electrochemical tests conducted at room temperature for Li/LiFePO4 cells using the hybrid electrolyte exhibited a high capacity of 150 mAh·g-1LFP at C/30, and still retained 60 mAh·g-1LFP at 1 C, while bare LATP does not perform well at low temperatures. These findings highlight this hybrid electrolyte as a superior alternative to the ceramic LATP electrolyte and a safer option compared with conventional organic electrolytes. Información suministrada por el agente en SIGEVAPalabras Clave
POROUS CERAMIC SUPPORTLI BATTERYIONIC LIQUIDHYBRID ELECTROLYTESQUASI-SOLID-STATE ELECTROLYTE