Science and Technology Production
Article
Authorship
SILBESTRI, GUSTAVO FABIAN
;
Bogel Masson, Romina
;
Lockhart, María Teresa
;
Chopa, Alicia Beatriz
Date
2006
Publishing House and Editing Place
Elsevier Science Sa
Magazine
JOURNAL OF ORGANOMETALLIC CHEMISTRY,
vol. 691
(pp. 1520-1524)
Elsevier Science Sa
Summary
Information provided by the agent in
SIGEVA
A series of diaryl ketones have been synthesized in good yields (40–78%) through the catalyst-free reaction of trimethylarylstannanes with aroyl chlorides in chlorobenzene as solvent. In addition, an attractive feature is that these reactions are completely regioselective making possible the synthesis of diarylketones which are not usually available under the influence of the directing forces of the substituents present in the aromatic ring. Also, the reaction conditions are mild enough t...
A series of diaryl ketones have been synthesized in good yields (40–78%) through the catalyst-free reaction of trimethylarylstannanes with aroyl chlorides in chlorobenzene as solvent. In addition, an attractive feature is that these reactions are completely regioselective making possible the synthesis of diarylketones which are not usually available under the influence of the directing forces of the substituents present in the aromatic ring. Also, the reaction conditions are mild enough to be applied to acid sensitive molecules.
Show more
Show less
Download or request the full text