Science and Technology Production
Article
Authorship
SALUM, MARIA LAURA
;
Robles, Cecilia J.
;
ERRA BALSELLS, ROSA
Date
2010
Publishing House and Editing Place
American Chemical Society
Magazine
ORGANIC LETTERS,
vol. 12
(pp. 4808-4811)
American Chemical Society
Summary
Information provided by the agent in
SIGEVA
Photoisomerization presents the only direct method for contra-thermodynamic E-Z isomerization of olefins. Synthetic applications of this method have been limited by its reversible nature, which leads to a photostationary-state mixture of both isomers. For the first time, a highly efficient one-pot preparation-isolation of solid ionic liquid Z-cinnamic acids by photoisomerization in acetonitrile solution of ionic liquid E-cinnamic acids is described.
Key Words
SYNTHESISCINNAMIC ACIDSIONIC LIQUIDPHOTOISOMERIZATION
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