Science and Technology Production
Article
Authorship
Germán E. Gomez
;
María C. Bernini
;
Elena V. Brusau
;
Griselda E. Narda
;
MASSAD, WALTER ALFREDO
;
Ana Labrador
Date
2013
Publishing House and Editing Place
AMER CHEMICAL SOC
Magazine
CRYSTAL GROWTH & DESIGN
AMER CHEMICAL SOC
Summary
Information provided by the agent in
SIGEVA
Reactions in aqueous solution under hydrothermal conditions between (±) 2,3-dimethylsuccinic acid and lanthanide chlorides lead to two different isostructural types with chemical formulae: [Ln2(C6H8O4)3(H2O)2] Ln(III) = Pr ? Eu (except Pm) (Type I, compounds 1-4) and [Ln2(C6H8O4)3] Ln(III) = Tb ? Yb (except Tm) (Type II, compounds 5-9). The crystal structure has been solved for the Pr (1), Sm (3) and Ho (7)-containing compounds by means of single-crystal XRD methods while powder XRD Riet...
Reactions in aqueous solution under hydrothermal conditions between (±) 2,3-dimethylsuccinic acid and lanthanide chlorides lead to two different isostructural types with chemical formulae: [Ln2(C6H8O4)3(H2O)2] Ln(III) = Pr ? Eu (except Pm) (Type I, compounds 1-4) and [Ln2(C6H8O4)3] Ln(III) = Tb ? Yb (except Tm) (Type II, compounds 5-9). The crystal structure has been solved for the Pr (1), Sm (3) and Ho (7)-containing compounds by means of single-crystal XRD methods while powder XRD Rietveld refinement was used for the rest of the MOFs. Compounds 1-4 crystallize in the triclinic space group Pī while compounds 5-9 belong to the tetragonal space group P43212. Type I and II compounds are 3D frameworks consisting of chains of [LnO8(H2O)] or [LnO8] polyhedra, respectively, linked by dimethylsuccinate anions, giving rise to I1O2 connectivity. All the compounds were characterized by X-ray diffraction, Variable?Temperature Fourier Transform Infrared Spectroscopy and thermal analysis. An exhaustive topological study was performed in comparison with other related compounds. The luminescent properties have been also explored for compounds 3, 4 and 5 including the emission spectra, lifetime measurements and the quantum yields have been calculated.
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Key Words
dimethylsuccinateluminiscencelanthanidetopological study