Science and Technology Production
Book Chapter
Authorship
R. Fausto, I. D. Reva y A. Gómez Zavaglia
Date
2007
Publishing House and Editing Place
Research Signpost
Book
Recent Research Developments in Heterocyclic Chemistry
(pp. 313-396)
Research Signpost
Research Signpost
ISBN
81-308-0169-8
Summary
Information provided by the agent in
SIGEVA
A brief description of the matrix isolation technique is presented, highlighting its advantages over other techniques when used in the investigation of molecular structure and reactivity. Illustrative examples of application of the method, together with conventional (non-time-resolved) infrared spectroscopy, for studies of selected families of heterocyclic compounds are discussed. These include thermally and photochemically induced conformational isomerization and tautomerization processes, rin...
A brief description of the matrix isolation technique is presented, highlighting its advantages over other techniques when used in the investigation of molecular structure and reactivity. Illustrative examples of application of the method, together with conventional (non-time-resolved) infrared spectroscopy, for studies of selected families of heterocyclic compounds are discussed. These include thermally and photochemically induced conformational isomerization and tautomerization processes, ring-opening reactions, rearrangements and fragmentation processes as well as aggregation. We address here a broad variety of compounds extending from 3- to 6-membered cycles, and including the elements oxygen, nitrogen and sulphur as heteroatoms.
Show more
Show less
Key Words
FTIRmatrix isolation spectroscopy